A theoretical study of EPR g factors for the rhombic CuCl(6)(4-) clusters in (3-chloroanilinium)(8) CdCl(6) Cl(4):Cu(2+) crystal

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	A theoretical study of EPR g factors for the rhombic CuCl(6)(4-) clusters in (3-chloroanilinium)(8) CdCl(6) Cl(4):Cu(2+) crystal
	D. T. Zhang; L. He; W. Q. Yang; W. C. Zheng
	2010
发表期刊	Physica B-Condensed Matter
ISSN	0921-4526
卷号	405 期号:17 页码:3642-3644
摘要	In this paper, the third-order perturbation formulas of EPR g factors g(i) (i=x, y, z) for d(9) ions in rhombic symmetry where the ground state being an vertical bar d(x2-y2)> admixture of and vertical bar d(z2)> states are derived. These formulas are based on a two-spin-orbit-parameter model in which the contributions to g factors due to both the spin-orbit parameter of the central 3d(n) ion and that of ligand ion are included. From these formulas, the g factors g(i) for the rhombic CuCl(6)(4-) clusters in (3-chloroanilinium)(8)[CdCl(6)]CL(4):Cu(2+) crystal are calculated. The calculated values are in good agreement with those obtained by the complete diagonalization (of energy matrix) method and experimental values. Results are discussed. (C) 2010 Elsevier B.V. All rights reserved.
部门归属	[zhang dong-ting; yang wei-qing; zheng wen-chen] sichuan univ, dept mat sci, chengdu 610064, peoples r china. [he lv] zhejiang normal univ, dept phys, jinhua 321004, peoples r china. [yang wei-qing] chengdu univ informat technol, dept opt & elect, chengdu 610225, peoples r china. [zheng wen-chen] chinese acad sci, int ctr mat phys, shenyang 110016, peoples r china.;zheng, wc (reprint author), sichuan univ, dept mat sci, chengdu 610064, peoples r china;zhengwc1@163.com
关键词	Electron Paramagnetic Resonance Crystal And ligAnd Field Theory Optical Spectrum (3-chloroanilinium)(8)[CdCl(6)]Cl(4):Cu(2+) Atomic Screening Constants Gyromagnetic Factor Single-crystals Scf Functions Cu2++ Ion Parameters Distortion Resonance Spectra Vo2++
URL	查看原文
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/31683
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	D. T. Zhang,L. He,W. Q. Yang,et al. A theoretical study of EPR g factors for the rhombic CuCl(6)(4-) clusters in (3-chloroanilinium)(8) CdCl(6) Cl(4):Cu(2+) crystal[J]. Physica B-Condensed Matter,2010,405(17):3642-3644.
APA	D. T. Zhang,L. He,W. Q. Yang,&W. C. Zheng.(2010).A theoretical study of EPR g factors for the rhombic CuCl(6)(4-) clusters in (3-chloroanilinium)(8) CdCl(6) Cl(4):Cu(2+) crystal.Physica B-Condensed Matter,405(17),3642-3644.
MLA	D. T. Zhang,et al."A theoretical study of EPR g factors for the rhombic CuCl(6)(4-) clusters in (3-chloroanilinium)(8) CdCl(6) Cl(4):Cu(2+) crystal".Physica B-Condensed Matter 405.17(2010):3642-3644.