Enhancement of the spin entropy in Na(x)Co(2)O(4) by Ni doping | |
G. D. Tang; T. Yang; X. N. Xu; C. P. Tang; L. Qiu; Z. D. Zhang; L. Y. Lv; Z. H. Wang; Y. W. Du | |
2010 | |
发表期刊 | Applied Physics Letters
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ISSN | 0003-6951 |
卷号 | 97期号:3 |
摘要 | The effects of Ni doping on the spin entropy in Na(x)Co(2)O(4) (x=1.2) has been carefully studied. A strong magnetic-field suppression of the thermopower indicates the emergence of large spin-entropy effect. The magnetothermopower increases with increasing Ni doping level, suggesting that Ni doping improves the spin entropy of Na(x)Co(2)O(4). Based on analysis of x-ray absorption spectra, we propose a spin-entropy competition mechanism to explain well the spin-entropy enhancement. (C) 2010 American Institute of Physics. [doi:10.1063/1.3467205] |
部门归属 | [tang, guodong; xu, xiaonong; tang, chipui; qiu, li; lv, liya; wang, zhihe; du, youwei] nanjing univ, natl lab solid state microstruct, dept phys, nanjing 210093, peoples r china. [yang, teng; zhang, zhidong] chinese acad sci, inst met res, natl lab mat sci, shenyang 110016, peoples r china. [yang, teng; zhang, zhidong] chinese acad sci, int ctr mat phys, shenyang 110016, peoples r china.;tang, gd (reprint author), nanjing univ, natl lab solid state microstruct, dept phys, nanjing 210093, peoples r china;zhwang@nju.edu.cn |
关键词 | Doping Profiles Entropy Magnetocaloric Effects Nickel Sodium Compounds Spin Dynamics X-ray Absorption Spectra Thermopower |
URL | 查看原文 |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/31469 |
专题 | 中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | G. D. Tang,T. Yang,X. N. Xu,et al. Enhancement of the spin entropy in Na(x)Co(2)O(4) by Ni doping[J]. Applied Physics Letters,2010,97(3). |
APA | G. D. Tang.,T. Yang.,X. N. Xu.,C. P. Tang.,L. Qiu.,...&Y. W. Du.(2010).Enhancement of the spin entropy in Na(x)Co(2)O(4) by Ni doping.Applied Physics Letters,97(3). |
MLA | G. D. Tang,et al."Enhancement of the spin entropy in Na(x)Co(2)O(4) by Ni doping".Applied Physics Letters 97.3(2010). |
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