Reactivity of Al-rich Alloys withWater Promoted by Liquid Al Grain Boundary Phases

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	Reactivity of Al-rich Alloys withWater Promoted by Liquid Al Grain Boundary Phases
	He, Tiantian; Wang, Wei; Chen, Wei; Chen, Demin; Yang, Ke; Wang, W; Chen, DM (reprint author), Chinese Acad Sci, Inst Met Res, Shenyang 110016, Peoples R China.
	2017-04-01
发表期刊	JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
ISSN	1005-0302
卷号	33 期号:4 页码:397-403
摘要	Al-Ga-Sn, Al-Ga-In and Al-Ga-In-Sn alloys were prepared using arc melting technique. Their microstructures were investigated by X-ray diffraction and scanning electron microscopy with energy dispersed X-ray. Based on microstructure analysis, the phase constituents of alloys at Al grain boundaries were identified. The melting points of Al grain boundary phases were measured using differential scanning calorimeter. The reactivities of Al-water at different water temperatures indicate that liquid Al grain boundary phases promote Al-water reactions of alloys. The melting points of Al grain boundary phases affect the reaction temperatures of Al-water, leading to different reaction temperatures of alloys. The measured H-2 generation rate and yields of alloys are related to the compositions of alloys. The theory of microgalvanic cell is used to explain the observed different H-2 generation rates of alloys. Copyright (C) 2017, The editorial office of Journal of Materials Science & Technology. Published by Elsevier Limited.; Al-Ga-Sn, Al-Ga-In and Al-Ga-In-Sn alloys were prepared using arc melting technique. Their microstructures were investigated by X-ray diffraction and scanning electron microscopy with energy dispersed X-ray. Based on microstructure analysis, the phase constituents of alloys at Al grain boundaries were identified. The melting points of Al grain boundary phases were measured using differential scanning calorimeter. The reactivities of Al-water at different water temperatures indicate that liquid Al grain boundary phases promote Al-water reactions of alloys. The melting points of Al grain boundary phases affect the reaction temperatures of Al-water, leading to different reaction temperatures of alloys. The measured H-2 generation rate and yields of alloys are related to the compositions of alloys. The theory of microgalvanic cell is used to explain the observed different H-2 generation rates of alloys. Copyright (C) 2017, The editorial office of Journal of Materials Science & Technology. Published by Elsevier Limited.
部门归属	[he, tiantian ; wang, wei ; chen, wei ; chen, demin ; yang, ke] chinese acad sci, inst met res, shenyang 110016, peoples r china
关键词	Al Alloy Microstructure Composition Reaction Hydrogen Generation Rate
学科领域	Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
资助者	National Science Foundation of China [51171201]; National Basic Research Program of China [2010CB631305]
收录类别	SCI
语种	英语
WOS记录号	WOS:000401089300011
引用统计	被引频次：35[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/78199
专题	中国科学院金属研究所
通讯作者	Wang, W; Chen, DM (reprint author), Chinese Acad Sci, Inst Met Res, Shenyang 110016, Peoples R China.
推荐引用方式 GB/T 7714	He, Tiantian,Wang, Wei,Chen, Wei,et al. Reactivity of Al-rich Alloys withWater Promoted by Liquid Al Grain Boundary Phases[J]. JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,2017,33(4):397-403.
APA	He, Tiantian.,Wang, Wei.,Chen, Wei.,Chen, Demin.,Yang, Ke.,...&Chen, DM .(2017).Reactivity of Al-rich Alloys withWater Promoted by Liquid Al Grain Boundary Phases.JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,33(4),397-403.
MLA	He, Tiantian,et al."Reactivity of Al-rich Alloys withWater Promoted by Liquid Al Grain Boundary Phases".JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY 33.4(2017):397-403.