Secondary batteries with multivalent ions for energy storage

IMR OpenIR

	Secondary batteries with multivalent ions for energy storage
	Xu, Chengjun; Chen, Yanyi; Shi, Shan; Li, Jia; Kang, Feiyu; Su, Dangsheng; vivaxuchengjun@163.com
	2015
发表期刊	SCIENTIFIC REPORTS
ISSN	2045-2322
卷号	5 页码:-
摘要	The use of electricity generated from clean and renewable sources, such as water, wind, or sunlight, requires efficiently distributed electrical energy storage by high-power and high-energy secondary batteries using abundant, low-cost materials in sustainable processes. American Science Policy Reports state that the next-generation "beyond-lithium" battery chemistry is one feasible solution for such goals. Here we discover new "multivalent ion" battery chemistry beyond lithium battery chemistry. Through theoretic calculation and experiment confirmation, stable thermodynamics and fast kinetics are presented during the storage of multivalent ions (Ni2+, Zn2+, Mg2+, Ca2+, Ba2+, or La3+ ions) in alpha type manganese dioxide. Apart from zinc ion battery, we further use multivalent Ni2+ ion to invent another rechargeable battery, named as nickel ion battery for the first time. The nickel ion battery generally uses an alpha type manganese dioxide cathode, an electrolyte containing Ni2+ ions, and Ni anode. The nickel ion battery delivers a high energy density (340 Wh kg(-1), close to lithium ion batteries), fast charge ability (1 minute), and long cycle life (over 2200 times).
部门归属	[xu, chengjun ; chen, yanyi ; shi, shan ; li, jia ; kang, feiyu] tsinghua univ, grad sch shenzhen, shenzhen 518055, peoples r china ; [shi, shan ; kang, feiyu] tsinghua univ, dept mat sci & engn, state key lab new ceram & fine proc, beijing 100084, peoples r china ; [su, dangsheng] max planck gesell, fritz haber inst, dept inorgan chem, d-14195 berlin, germany ; [su, dangsheng] chinese acad sci, inst met res, shenyang natl lab mat sci, shenyang 110016, peoples r china
资助者	NSFC [51102139]; Shenzhen Technical Plan Projects [JC201105201100A, JCYJ20130402145002425]; Guangdong Province Innovation RD Team Plan [2009010025]
收录类别	sci
语种	英语
WOS记录号	WOS:000361151400001
引用统计	被引频次：148[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/75108
专题	中国科学院金属研究所
通讯作者	vivaxuchengjun@163.com
推荐引用方式 GB/T 7714	Xu, Chengjun,Chen, Yanyi,Shi, Shan,et al. Secondary batteries with multivalent ions for energy storage[J]. SCIENTIFIC REPORTS,2015,5:-.
APA	Xu, Chengjun.,Chen, Yanyi.,Shi, Shan.,Li, Jia.,Kang, Feiyu.,...&vivaxuchengjun@163.com.(2015).Secondary batteries with multivalent ions for energy storage.SCIENTIFIC REPORTS,5,-.
MLA	Xu, Chengjun,et al."Secondary batteries with multivalent ions for energy storage".SCIENTIFIC REPORTS 5(2015):-.