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Sulfonated Poly(Ether Ether Ketone)/Functionalized Carbon Nanotube Composite Membrane for Vanadium Redox Flow Battery Applications
C. K.; Cheng Jia, Y. H.; Ling, X.; Wei, G. J.; Liu, J. G.; Yan, C. W.
2015
发表期刊Electrochimica Acta
ISSN0013-4686
卷号153页码:44-48
摘要A novel sulfonated poly(ether ether ketone) (SPEEK) membrane embedded with the short-carboxylic multi-walled carbon nanotube (we name it as SPEEK/SCCT membrane) for vanadium redox flow battery (VRB) has been prepared with low capacity loss, low cost and high energy efficiency. The mechanical strength, vanadium ions permeability and performance of the membrane in the VRB single cell were characterized. Results showed that the SPEEK/SCCT membrane possessed low permeability of vanadium ions, accompanied by higher mechanical strength than the Nafion 212 membrane. The VRB single cell with SPEEK/SCCT membrane showed 7% higher coulombic efficiency (CE), 6% higher energy efficiency (EE) but lower capacity loss in comparison with the one with Nafion 212. The good cell performance, low capacity loss and high vanadium ions barrier properties of the blend membrane is of significant interest for VRB applications. (C) 2014 Elsevier Ltd. All rights reserved.
部门归属[jia, chuankun ; cheng, yuanhang ; ling, xiao ; wei, guanjie ; liu, jianguo ; yan, chuanwei] chinese acad sci, inst met res, shenyang 110016, peoples r china. ; jia, ck (reprint author), chinese acad sci, inst met res, shenyang 110016, peoples r china. ; jack2012ding@gmail.com ; cwyan@imr.ac.cn
关键词Sulfonated Poly(Ether Ether Ketone) Vanadium Redox Flow Battery Proton Exchange Membrane Short-carboxylic Multi-walled Carbon Nanotube Nafion Proton-exchange Membranes Fuel-cells
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文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/73827
专题中国科学院金属研究所
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GB/T 7714
C. K.,Cheng Jia, Y. H.,Ling, X.,et al. Sulfonated Poly(Ether Ether Ketone)/Functionalized Carbon Nanotube Composite Membrane for Vanadium Redox Flow Battery Applications[J]. Electrochimica Acta,2015,153:44-48.
APA C. K.,Cheng Jia, Y. H.,Ling, X.,Wei, G. J.,Liu, J. G.,&Yan, C. W..(2015).Sulfonated Poly(Ether Ether Ketone)/Functionalized Carbon Nanotube Composite Membrane for Vanadium Redox Flow Battery Applications.Electrochimica Acta,153,44-48.
MLA C. K.,et al."Sulfonated Poly(Ether Ether Ketone)/Functionalized Carbon Nanotube Composite Membrane for Vanadium Redox Flow Battery Applications".Electrochimica Acta 153(2015):44-48.
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