Nanostructured titania have been intensively investigated as anode materials of Li-ion batteries for their excellent high rate performance. The size effects of TiO2 polymorphs (mainly rutile, anatase and TiO2-B) on their electrochemical performance and the latest efforts in nanoengineering titania anodes through enhancing their ionic or electronic transportation or both are reviewed in this work. We suppose that micron- or submicron-sized porous structures assembled by TiO2 nanoparticles, nanowires/nanotubes or nanosheets with a high percentage of exposing high reactive facets together with a conductive percolating network are ideal anodes not only for high rate lithium storage but also for high packing densities of the active materials.
部门归属
[jiang, chunhai
; zhang, jinsong] chinese acad sci, inst met res, shenyang 110016, peoples r china.
; jiang, ch (reprint author), chinese acad sci, inst met res, shenyang 110016, peoples r china.
; chjiang@imr.ac.cn
; jshzhang@imr.ac.cn
C. H. Jiang,J. S. Zhang. Nanoengineering Titania for High Rate Lithium Storage: A Review[J]. Journal of Materials Science & Technology,2013,29(2):97-122.
APA
C. H. Jiang,&J. S. Zhang.(2013).Nanoengineering Titania for High Rate Lithium Storage: A Review.Journal of Materials Science & Technology,29(2),97-122.
MLA
C. H. Jiang,et al."Nanoengineering Titania for High Rate Lithium Storage: A Review".Journal of Materials Science & Technology 29.2(2013):97-122.
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