Effect of milling atmosphere on the hydriding properties of a Mg-amorphous Zr0.9Ti0.1(Ni-0.57 Mn0.28V0.1Co0.05)(2.1) composite; Effect of milling atmosphere on the hydriding properties of a Mg-amorphous Zr0.9Ti0.1(Ni-0.57 Mn0.28V0.1Co0.05)(2.1) composite | |
H. Y. Leng; D. M. Chen; M. Q. Lu; H. F. Zhang; H. M. Cheng; K. Yang | |
2003 ; 2003 | |
发表期刊 | Journal of Alloys and Compounds
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ISSN | 0925-8388 ; 0925-8388 |
卷号 | 361期号:1-2页码:276-281 |
摘要 | The effect of milling atmosphere on the hydriding properties of a Mg-amorphous Zr0.9Ti0.1(Ni0.57Mn0.28V0.1Co0.05)(2.1) composite milled with a Spex8000 vibration mill was investigated by X-ray powder diffraction, SEM and TEM. The results indicated that, compared with the composite milled under Ar, the composite milled under H-2 showed superior hydriding performance. The brittle MgH2, which formed directly during the milling process under H-2 with the help of the amorphous phase Zr0.9Ti0.1(Ni0.57Mn0.28V0.1Co0.05)(2.1) and the mechanical driving force, resulted in a highly dispersive distribution of the amorphous phase in the Mg matrix and a smaller particle/grain size during the RMA process, which led to a remarkable decrease in the activation energy for hydrogen absorption. (C) 2003 Elsevier B.V. All rights reserved.; The effect of milling atmosphere on the hydriding properties of a Mg-amorphous Zr0.9Ti0.1(Ni0.57Mn0.28V0.1Co0.05)(2.1) composite milled with a Spex8000 vibration mill was investigated by X-ray powder diffraction, SEM and TEM. The results indicated that, compared with the composite milled under Ar, the composite milled under H-2 showed superior hydriding performance. The brittle MgH2, which formed directly during the milling process under H-2 with the help of the amorphous phase Zr0.9Ti0.1(Ni0.57Mn0.28V0.1Co0.05)(2.1) and the mechanical driving force, resulted in a highly dispersive distribution of the amorphous phase in the Mg matrix and a smaller particle/grain size during the RMA process, which led to a remarkable decrease in the activation energy for hydrogen absorption. (C) 2003 Elsevier B.V. All rights reserved. |
部门归属 | chinese acad sci, inst met res, shenyang 110016, peoples r china.;leng, hy (reprint author), chinese acad sci, inst met res, shenyang 110016, peoples r china ; chinese acad sci, inst met res, shenyang 110016, peoples r china.;leng, hy (reprint author), chinese acad sci, inst met res, shenyang 110016, peoples r china |
关键词 | Transition Metal Compounds Transition Metal Compounds Hydrogen Absorbing Materials Hydrogen Absorbing Materials Metal Metal Hydrides Hydrides Mechanical Alloying Mechanical Alloying Gas-solid Reactions Gas-solid Reactions Hydrogen Absorption Properties Hydrogen Absorption Properties Storage Storage Magnesium Magnesium Sorption Sorption Alloys Alloys System System Co Co Fe Fe Ni Ni |
URL | 查看原文 ; 查看原文 |
WOS记录号 | WOS:000186125800046 ; WOS:000186125800046 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/35879 |
专题 | 中国科学院金属研究所 |
推荐引用方式 GB/T 7714 | H. Y. Leng,D. M. Chen,M. Q. Lu,et al. Effect of milling atmosphere on the hydriding properties of a Mg-amorphous Zr0.9Ti0.1(Ni-0.57 Mn0.28V0.1Co0.05)(2.1) composite, Effect of milling atmosphere on the hydriding properties of a Mg-amorphous Zr0.9Ti0.1(Ni-0.57 Mn0.28V0.1Co0.05)(2.1) composite[J]. Journal of Alloys and Compounds, Journal of Alloys and Compounds,2003, 2003,361, 361(1-2):276-281, 276-281. |
APA | H. Y. Leng,D. M. Chen,M. Q. Lu,H. F. Zhang,H. M. Cheng,&K. Yang.(2003).Effect of milling atmosphere on the hydriding properties of a Mg-amorphous Zr0.9Ti0.1(Ni-0.57 Mn0.28V0.1Co0.05)(2.1) composite.Journal of Alloys and Compounds,361(1-2),276-281. |
MLA | H. Y. Leng,et al."Effect of milling atmosphere on the hydriding properties of a Mg-amorphous Zr0.9Ti0.1(Ni-0.57 Mn0.28V0.1Co0.05)(2.1) composite".Journal of Alloys and Compounds 361.1-2(2003):276-281. |
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