EPR investigation of local structure for Mn(H(2)O)(6) (2+) cluster in M(H(2)O)(6) XCl(6): Mn(2+) (M = Zn, Mg, Cd, Ca; X = Pt, Sn) systems at different temperatures

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	EPR investigation of local structure for Mn(H(2)O)(6) (2+) cluster in M(H(2)O)(6) XCl(6): Mn(2+) (M = Zn, Mg, Cd, Ca; X = Pt, Sn) systems at different temperatures
	W. Y. Tian; X. Y. Kuang; H. F. Li; Y. F. Li; Li Ying
	2009
发表期刊	Chemical Physics Letters
ISSN	0009-2614
卷号	468 期号:4-6 页码:325-329
摘要	A theoretical method for studying the inter-relation between the local structure and EPR spectra is established by diagonalizing the complete energy matrices. For [M(H(2)O)(6)]XCl(6): Mn(2+) (M = Zn, Mg, Cd, Ca; X = Pt, Sn) systems, the calculated results demonstrate that the local structures around the octahedral Mn(2+) centers in the doped systems are very similar despite of the host crystals being different. Furthermore, it is shown that the EPR zero-field parameter D depends simultaneously on the local structure parameters R and h while (a - F) depends mainly on R, whether the doped systems are at liquid-nitrogen temperature or room temperature. (C) 2008 Elsevier B.V. All rights reserved.
部门归属	[tian, wen-yan; kuang, xiao-yu; li, hui-fang; li, yan-fang; ying-li] sichuan univ, inst atom & mol phys, chengdu 610065, peoples r china. [kuang, xiao-yu] acad sinica, int ctr mat phys, shenyang 110016, peoples r china.;kuang, xy (reprint author), sichuan univ, inst atom & mol phys, chengdu 610065, peoples r china;scu_kuang@163.com
关键词	Electron-paramagnetic-resonance Single-crystals Spectra Field Ions Spectroscopy Copper(Ii) Complexes Behavior Mn(Ii)
URL	查看原文
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/32331
专题	中国科学院金属研究所
推荐引用方式 GB/T 7714	W. Y. Tian,X. Y. Kuang,H. F. Li,et al. EPR investigation of local structure for Mn(H(2)O)(6) (2+) cluster in M(H(2)O)(6) XCl(6): Mn(2+) (M = Zn, Mg, Cd, Ca; X = Pt, Sn) systems at different temperatures[J]. Chemical Physics Letters,2009,468(4-6):325-329.
APA	W. Y. Tian,X. Y. Kuang,H. F. Li,Y. F. Li,&Li Ying.(2009).EPR investigation of local structure for Mn(H(2)O)(6) (2+) cluster in M(H(2)O)(6) XCl(6): Mn(2+) (M = Zn, Mg, Cd, Ca; X = Pt, Sn) systems at different temperatures.Chemical Physics Letters,468(4-6),325-329.
MLA	W. Y. Tian,et al."EPR investigation of local structure for Mn(H(2)O)(6) (2+) cluster in M(H(2)O)(6) XCl(6): Mn(2+) (M = Zn, Mg, Cd, Ca; X = Pt, Sn) systems at different temperatures".Chemical Physics Letters 468.4-6(2009):325-329.