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Enhanced Arsenite Adsorption onto Litchi-Like Al-Doped Iron Oxides
R. H. Li; Q. Li; S. A. Gao; J. K. Shang
2011
发表期刊Journal of the American Ceramic Society
ISSN0002-7820
卷号94期号:2页码:584-591
摘要Iron-aluminum complex hydroxide/oxides were synthesized from a hydrothermal process, and litchi-like Al-doped iron oxide nanoparticles were then obtained by removing extra boehmite nanoplates with NaOH washing. While the hydrothermal synthesis induced doping of iron oxide by Al, with the Al dopant concentration increasing with the Al-Fe molar ratio, removal of boehmite greatly increased the specific surface area (SSA) of these Al-doped iron oxide nanoparticles. The resulting litchi-like Al-doped iron oxide nanoparticles were found to strongly adsorb As(III) from aqueous environment at neutral pH without preoxidation., and the As(III) (arsenite) adsorption capacity of Al-doped iron oxides increased with the increase of the initial ratio of Al/Fe in the hydrothermal process, reaching as high as 2.5 times the adsorption capacity of pure iron oxide. The enhanced arsenite adsorption was shown to result from the increases in the amount of the surface hydroxyl group as well as in the SSA of Al-doped iron oxide nanoparticles.
部门归属[li, ronghui; li, qi; gao, shian; shang, jian ku] chinese acad sci, mat ctr water purificat, inst met res, shenyang 110016, peoples r china. [shang, jian ku] univ illinois, dept mat sci & engn, urbana, il 61801 usa.;shang, jk (reprint author), chinese acad sci, mat ctr water purificat, inst met res, shenyang 110016, peoples r china;jkshang@illinois.edu
关键词Arsenate Adsorption Mesoporous Alumina Surface-properties Activated Alumina Inner-sphere Alpha-feooh Removal Goethite Adsorbent Water
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WOS记录号WOS:000286830100048
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被引频次:23[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/30481
专题中国科学院金属研究所
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R. H. Li,Q. Li,S. A. Gao,et al. Enhanced Arsenite Adsorption onto Litchi-Like Al-Doped Iron Oxides[J]. Journal of the American Ceramic Society,2011,94(2):584-591.
APA R. H. Li,Q. Li,S. A. Gao,&J. K. Shang.(2011).Enhanced Arsenite Adsorption onto Litchi-Like Al-Doped Iron Oxides.Journal of the American Ceramic Society,94(2),584-591.
MLA R. H. Li,et al."Enhanced Arsenite Adsorption onto Litchi-Like Al-Doped Iron Oxides".Journal of the American Ceramic Society 94.2(2011):584-591.
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