| Lithium oxides LiRO2 (R = rare earth elements) with negative thermal expansion behavior and inverse barocaloric effect | |
| Qu, Lin1,2,3,4; Abbas, Muhammad Tahir1,2; Zhang, Kun1,2; Zhang, Zhe1,2; Yang, Teng1,2; Zhang, Zhao1,2; Liu, Peng1,2; Qi, Ji1,2; Guo, Qing2,5; Li, Wanwu1,2; Zhao, Xueting1,2; Wang, Yanxu1,2; Zhang, Zhidong1,2; Li, Bing1,2 | |
| 通讯作者 | Zhang, Kun(kzhang@imr.ac.cn) ; Li, Bing(bingli@imr.ac.cn) |
| 2024-05-01 | |
| 发表期刊 | JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
 |
| ISSN | 2238-7854 |
| 卷号 | 30页码:9084-9092 |
| 摘要 | Negative thermal expansion (NTE) defies the conventional wisdom of lattice dynamics and offers a novel way to control the expansion coefficient and address some challenges in modern science and technology. From an application standpoint, materials exhibiting NTE across a broad temperature range, including room temperature, are highly sought after. In this work, we propose the multi-doping strategy and prepared a series of rare-earthbased lithium oxides featuring negative thermal expansion, with the objective of adjusting their temperature range. The phase transition temperatures of these materials range from 202 K to 467 K, demonstrating a linear correlation with the average ionic radius of the rare-earth elements. By capitalizing on the synergistic effects of four rare-earth elements, we expand the full width at half maximum of the thermal expansion peak in Li(ErYHoDy)0.25O2 from 1.6 K to 14.5 K, a notable improvement of nearly tenfold is achieved. Additionally, we investigate the low-temperature magnetocaloric effects and inverse barocaloric effects within these rare-earthbased lithium oxides. Temperature- and pressure-dependent Raman scattering measurements indicate that the phase transitions and the barocaloric effects are associated with the stretching mode of the Li-O bond and the vibrational mode of the YO6 octahedron. |
| 关键词 | Negative thermal expansion Widening operating-temperature window Inverse barocaloric effect Rare earth elements doping |
| 资助者 | Key Research Program of Frontier Sciences of Chinese Academy of Sciences ; Liaoning Provincial Science Fund for Distinguished Young Scholar ; Young Innovation Talent Program of Shenyang ; Ministry of Science and Technology of China ; IMR Innovation Fund ; National Natural Science Foundation of China ; International Partner Program of Chinese Academy of Sciences |
| DOI | 10.1016/j.jmrt.2024.05.251 |
| 收录类别 | SCI |
| 语种 | 英语 |
| 资助项目 | Key Research Program of Frontier Sciences of Chinese Academy of Sciences[ZDBS-LY-JSC002] ; Liaoning Provincial Science Fund for Distinguished Young Scholar ; Young Innovation Talent Program of Shenyang[RC210432] ; Ministry of Science and Technology of China[2021YFB3501201] ; Ministry of Science and Technology of China[2022YFE0109900] ; IMR Innovation Fund ; National Natural Science Foundation of China[11934007] ; National Natural Science Foundation of China[52001101] ; National Natural Science Foundation of China[52201029] ; International Partner Program of Chinese Academy of Sciences[174321KYSB20200008] |
| WOS研究方向 | Materials Science ; Metallurgy & Metallurgical Engineering |
| WOS类目 | Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering |
| WOS记录号 | WOS:001255491000001 |
| 出版者 | ELSEVIER |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.imr.ac.cn/handle/321006/187582 |
| 专题 | 中国科学院金属研究所 |
| 通讯作者 | Zhang, Kun; Li, Bing |
| 作者单位 | 1.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China 2.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 3.Univ Sci & Technol China, Sch Chem & Mat Sci, Hefei 230026, Peoples R China 4.Univ Sci & Technol China, Suzhou Inst Adv Res, Suzhou 215123, Peoples R China 5.Bohai Univ, Coll Phys Sci & Technol, Jinzhou 121013, Peoples R China |
| 推荐引用方式 GB/T 7714 | Qu, Lin,Abbas, Muhammad Tahir,Zhang, Kun,et al. Lithium oxides LiRO2 (R = rare earth elements) with negative thermal expansion behavior and inverse barocaloric effect[J]. JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T,2024,30:9084-9092. |
| APA | Qu, Lin.,Abbas, Muhammad Tahir.,Zhang, Kun.,Zhang, Zhe.,Yang, Teng.,...&Li, Bing.(2024).Lithium oxides LiRO2 (R = rare earth elements) with negative thermal expansion behavior and inverse barocaloric effect.JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T,30,9084-9092. |
| MLA | Qu, Lin,et al."Lithium oxides LiRO2 (R = rare earth elements) with negative thermal expansion behavior and inverse barocaloric effect".JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T 30(2024):9084-9092. |
| 条目包含的文件 | 条目无相关文件。 | |||||
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