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Liquid-solid phase separation and recycling of permalloys in liquid Mg
Yang, Pengju1,2,3; He, Jie1,3; You, Baodong1,2; Zhu, Mingwei2; Wang, Shaogang4; Kaban, Ivan5; Zhao, Jiuzhou1,3
通讯作者He, Jie(jiehe@imr.ac.cn) ; Zhu, Mingwei(mwzhu@sau.edu.cn)
2024-07-20
发表期刊JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
ISSN1005-0302
卷号188页码:27-36
摘要Liquid-solid phase separation of permalloy in liquid Mg results in selectively dissolved Ni, which provides a unique opportunity for the design of immiscible heterogeneous composite materials and the comprehensive metal recycling of permalloy scraps. A guideline of the alloy design for the liquid-solid phase separation system was proposed. The effects of immersion temperature and time on the Ni extraction were studied by an experimental method. The diffusion behavior of Ni from the permalloy to liquid Mg and the microstructure evolution in the permalloy during the liquid-solid phase separation were discussed. The results show that the Ni in the permalloy was quickly extracted into the liquid Mg and formed an Mg-Ni alloy, while the other components such as Fe, Co, and Mn were held back in the phase-separated permalloy. The phase-separated permalloy with the solidified Mg exhibits a three-dimensional (3D) Fe/Mg bicontinuous composite structure. Furthermore, simple treatments were carried out for the reaction products such as the Fe/Mg bicontinuous composite and the Mg-Ni alloy, and the recycling strategies for functionalization of these treated reaction products were provided. A 3D porous Fe-based alloy with electromagnetic interference (EMI) shielding efficiency of 52 dB can be obtained if Mg is removed from the Fe/Mg bicontinuous composite. Instead of the complete separation of pure Ni from the recycled Mg-Ni alloy by vacuum distilling, the Mg-Ni alloy can be enriched into Mg2 Ni as an initial hydrogen storage material. (c) 2024 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.
关键词Immiscible alloys Liquid-solid phase separation Permalloy Selective extraction Recycling
资助者Space Application Sys- tem of China Manned Space Program ; National Natural Science Foundation of China ; Scientific Instrument Developing Project of the Chi- nese Academy of Sciences ; IMR In- novation Fund
DOI10.1016/j.jmst.2023.11.028
收录类别SCI
语种英语
资助项目Space Application Sys- tem of China Manned Space Program[KJZ-YY-NCL06] ; National Natural Science Foundation of China[51974288] ; National Natural Science Foundation of China[52174280] ; Scientific Instrument Developing Project of the Chi- nese Academy of Sciences[YJKYYQ20210012] ; IMR In- novation Fund[E255A901]
WOS研究方向Materials Science ; Metallurgy & Metallurgical Engineering
WOS类目Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
WOS记录号WOS:001175808500001
出版者JOURNAL MATER SCI TECHNOL
引用统计
被引频次:2[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/184941
专题中国科学院金属研究所
通讯作者He, Jie; Zhu, Mingwei
作者单位1.Chinese Acad Sci, Inst Met Res, Shi Changxu Innovat Ctr Adv Mat, Shenyang 110016, Peoples R China
2.Shenyang Aerosp Univ, Sch Mat Sci & Engn, Shenyang 110136, Peoples R China
3.Univ Sci & Technol China, Sch Mat Sci & Engn, Shenyang 110016, Peoples R China
4.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
5.Leibniz Inst Solid State & Mat Res IFW Dresden, Helmholtzstr 20, D-01069 Dresden, Germany
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Yang, Pengju,He, Jie,You, Baodong,et al. Liquid-solid phase separation and recycling of permalloys in liquid Mg[J]. JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,2024,188:27-36.
APA Yang, Pengju.,He, Jie.,You, Baodong.,Zhu, Mingwei.,Wang, Shaogang.,...&Zhao, Jiuzhou.(2024).Liquid-solid phase separation and recycling of permalloys in liquid Mg.JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY,188,27-36.
MLA Yang, Pengju,et al."Liquid-solid phase separation and recycling of permalloys in liquid Mg".JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY 188(2024):27-36.
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