Study of the passivation and repassivation behavior of pure titanium in 3.5 wt NaCl solution and 6 M HNO3 solution | |
Chen, Qiqian1,2; Xu, Yanting1,2; Ma, Aili2,3; Zhang, Lianmin2; Zheng, Yugui2,3 | |
通讯作者 | Ma, Aili(alma@imr.ac.cn) ; Zheng, Yugui(ygzheng@imr.ac.cn) |
2023-11-01 | |
发表期刊 | CORROSION SCIENCE
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ISSN | 0010-938X |
卷号 | 224页码:13 |
摘要 | We reveal differences in composition and structure of passive films and repassivation rate of titanium in 3.5 wt% NaCl and in 6 M HNO3. Titanium in 6 M HNO3 shows worse corrosion resistance than in 3.5 wt% NaCl due to higher defect concentration and lower TiO2 content despite the thicker passive film, which is the result of accelerated cathodic process and promoted dissolution/formation dynamic equilibrium of passive film in 6 M HNO3. Repassivation rate in 3.5 wt% NaCl is higher although film growth rate is lower, as the film exhibits good barrier effect when it is thin. Our results provide insights needed to guide application of titanium in SNFR plants. |
关键词 | Titanium Polarization Scratching electrode Acid corrosion Passive films Repassivation |
资助者 | National Natural Science Foundation of China |
DOI | 10.1016/j.corsci.2023.111538 |
收录类别 | SCI |
语种 | 英语 |
资助项目 | National Natural Science Foundation of China[52171087] |
WOS研究方向 | Materials Science ; Metallurgy & Metallurgical Engineering |
WOS类目 | Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering |
WOS记录号 | WOS:001081792800001 |
出版者 | PERGAMON-ELSEVIER SCIENCE LTD |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.imr.ac.cn/handle/321006/179510 |
专题 | 中国科学院金属研究所 |
通讯作者 | Ma, Aili; Zheng, Yugui |
作者单位 | 1.Univ Sci & Technol China, Sch Mat Sci & Engn, 72 Wenhua Rd, Shenyang 110016, Peoples R China 2.Chinese Acad Sci, Inst Met Res, CAS Key Lab Nucl Mat & Safety Assessment, 62 Wencui Rd, Shenyang 110016, Peoples R China 3.Inst Met Sci & Technol, Chinese Acad Sci, 62 Wencui Rd, Shenyang 110016, Peoples R China |
推荐引用方式 GB/T 7714 | Chen, Qiqian,Xu, Yanting,Ma, Aili,et al. Study of the passivation and repassivation behavior of pure titanium in 3.5 wt NaCl solution and 6 M HNO3 solution[J]. CORROSION SCIENCE,2023,224:13. |
APA | Chen, Qiqian,Xu, Yanting,Ma, Aili,Zhang, Lianmin,&Zheng, Yugui.(2023).Study of the passivation and repassivation behavior of pure titanium in 3.5 wt NaCl solution and 6 M HNO3 solution.CORROSION SCIENCE,224,13. |
MLA | Chen, Qiqian,et al."Study of the passivation and repassivation behavior of pure titanium in 3.5 wt NaCl solution and 6 M HNO3 solution".CORROSION SCIENCE 224(2023):13. |
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