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A colossal barocaloric effect induced by the creation of a high-pressure phase
Zhang, Zhao1,2; Jiang, Xiaoming3; Hattori, Takanori4; Xu, Xiong5; Li, Min5; Yu, Chenyang1,2; Zhang, Zhe1,2; Yu, Dehong6; Mole, Richard6; Yano, Shin-ichiro7; Chen, Jie8; He, Lunhua8,9,10; Wang, Chin-Wei7; Wang, Hui5; Li, Bing1,2; Zhang, Zhidong1,2
通讯作者Wang, Hui(huiwang@csu.edu.cn) ; Li, Bing(bingli@imr.ac.cn)
2023-01-13
发表期刊MATERIALS HORIZONS
ISSN2051-6347
页码6
摘要As a promising environment-friendly alternative to current vapor-compression refrigeration, solid-state refrigeration based on the barocaloric effect has been attracting worldwide attention. Generally, both phases in which a barocaloric effect occurs are present at ambient pressure. Here, instead, we demonstrate that KPF6 exhibits a colossal barocaloric effect due to the creation of a high-pressure rhombohedral phase. The phase diagram is constructed based on pressure-dependent calorimetric, Raman scattering, and neutron diffraction measurements. The present study is expected to provide an alternative routine to colossal barocaloric effects through the creation of a high-pressure phase.
资助者Ministry of Science and Technology of China ; Key Research Program of Frontier Sciences of Chinese Academy of Sciences ; International Partner Program of Chinese Academy of Sciences ; IMR Innovation Fund ; Young Innovation Talent Program of Shenyang ; National Natural Science Foundation of China ; Distinguished Youth Foundation ; Key Research and Development Program of Hunan Province ; Youth Innovation Promotion Association of the Chinese Academy of Sciences ; CSNS Consortium on High-performance Materials of Chinese Academy of Sciences
DOI10.1039/d2mh00905f
收录类别SCI
语种英语
资助项目Ministry of Science and Technology of China[2022YFE0109900] ; Ministry of Science and Technology of China[2021YFB3501201] ; Key Research Program of Frontier Sciences of Chinese Academy of Sciences[ZDBS-LY-JSC002] ; International Partner Program of Chinese Academy of Sciences[174321KYSB20200008] ; IMR Innovation Fund ; Young Innovation Talent Program of Shenyang[RC210435] ; National Natural Science Foundation of China[11934007] ; National Natural Science Foundation of China[11804346] ; National Natural Science Foundation of China[11874429] ; National Natural Science Foundation of China[12174450] ; National Natural Science Foundation of China[2022WK2002] ; Distinguished Youth Foundation[22175172] ; Key Research and Development Program of Hunan Province[2020JJ2039] ; Youth Innovation Promotion Association of the Chinese Academy of Sciences[2020303] ; CSNS Consortium on High-performance Materials of Chinese Academy of Sciences
WOS研究方向Chemistry ; Materials Science
WOS类目Chemistry, Multidisciplinary ; Materials Science, Multidisciplinary
WOS记录号WOS:000912799000001
出版者ROYAL SOC CHEMISTRY
引用统计
被引频次:26[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/175210
专题中国科学院金属研究所
通讯作者Wang, Hui; Li, Bing
作者单位1.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China
2.Univ Sci & Technol China, Sch Mat Sci & Engn, 72 Wenhua Rd, Shenyang 110016, Liaoning, Peoples R China
3.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
4.Japan Atom Energy Agcy, J PARC Ctr, Naka, Ibaraki 3191195, Japan
5.Cent South Univ, Sch Phys & Elect, Hunan Key Lab Super Microstruct & Ultrafast Proc, State Key Lab Powder Met, Changsha 410083, Peoples R China
6.Lucas Hts, Australian Nucl Sci & Technol Org, Menai, NSW 2234, Australia
7.Natl Synchrotron Radiat Res Ctr, Hsinchu 30076, Taiwan
8.Spallat Neutron Source Sci Ctr, Dongguan 523803, Peoples R China
9.Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100190, Peoples R China
10.Songshan Lake Mat Lab, Dongguan 523808, Peoples R China
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GB/T 7714
Zhang, Zhao,Jiang, Xiaoming,Hattori, Takanori,et al. A colossal barocaloric effect induced by the creation of a high-pressure phase[J]. MATERIALS HORIZONS,2023:6.
APA Zhang, Zhao.,Jiang, Xiaoming.,Hattori, Takanori.,Xu, Xiong.,Li, Min.,...&Zhang, Zhidong.(2023).A colossal barocaloric effect induced by the creation of a high-pressure phase.MATERIALS HORIZONS,6.
MLA Zhang, Zhao,et al."A colossal barocaloric effect induced by the creation of a high-pressure phase".MATERIALS HORIZONS (2023):6.
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