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PPy coated nanoflower like CuCo2O4 based on in situ growth of nanoporous copper for high-performance supercapacitor electrodes
Zhao, Zongchen1; Zheng, Lili2; Li, Haoran1; He, Zeyin1; Han, Dong1; Shi, Jing1; Xu, Bin3,4; Wang, Huanlei1
通讯作者Shi, Jing(shijing@ouc.edu.cn) ; Xu, Bin(bxu@imr.ac.cn)
2022-04-09
发表期刊NANOTECHNOLOGY
ISSN0957-4484
卷号33期号:15页码:11
摘要General CuCo2O4 electrodes suffer a very low reversible capacity and poor cycling stability because of easily fading phenomena and volume change during cycling. To optimize the electrode, a facile method is conducted to fabricate a novel electrode of Cu@CuCo2O4@polypyrrole nanoflowers. Due to larger specific surface area and more electrochemical reactive areas of CuCo2O4@polypyrrole nanoflowers, the pseudocapacitance of the in situ grown CuCo2O4@polypyrrole (912 F g(-1) at 2 A g(-1)) is much higher than the pristine CuCo2O4 (618 F g(-1) at 2 A g(-1)). Remarkably, the CuCo2O4@polypyrrole (cathode) and active carbon (anode) are used to assemble an asymmetric supercapacitor, which exhibits a relatively high energy density of 90 Wh kg(-1) at a power density of 2519 W kg(-1) and 35 Wh kg(-1) at a high-power density of 9109 W kg(-1), and excellent cycling stability (about 90.4% capacitance retention over 10 000 cycles). The prominent performance of CuCo2O4@polypyrrole makes it as a potential electrode for supercapacitor.
关键词CuCo2O4 PPy nanoporous copper supercapacitor
资助者National Natural Science Foundation of China ; Natural Science Foundation of Shandong Province
DOI10.1088/1361-6528/ac4660
收录类别SCI
语种英语
资助项目National Natural Science Foundation of China[52001179] ; Natural Science Foundation of Shandong Province[ZR2020ME019]
WOS研究方向Science & Technology - Other Topics ; Materials Science ; Physics
WOS类目Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied
WOS记录号WOS:000744269700001
出版者IOP Publishing Ltd
引用统计
被引频次:11[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/173615
专题中国科学院金属研究所
通讯作者Shi, Jing; Xu, Bin
作者单位1.Ocean Univ China, Sch Mat Sci & Engn, Qingdao 266100, Peoples R China
2.Qingdao Univ, Coll Mech & Elect Engn, Natl Engn Res Ctr Intelligent Elect Vehicle Power, Qingdao 266071, Peoples R China
3.Chinese Acad Sci, Inst Met Res, Shengyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China
4.Chinese Acad Sci, Inst Met Res, Key Lab Nucl Mat & Safety, Shenyang 11016, Peoples R China
推荐引用方式
GB/T 7714
Zhao, Zongchen,Zheng, Lili,Li, Haoran,et al. PPy coated nanoflower like CuCo2O4 based on in situ growth of nanoporous copper for high-performance supercapacitor electrodes[J]. NANOTECHNOLOGY,2022,33(15):11.
APA Zhao, Zongchen.,Zheng, Lili.,Li, Haoran.,He, Zeyin.,Han, Dong.,...&Wang, Huanlei.(2022).PPy coated nanoflower like CuCo2O4 based on in situ growth of nanoporous copper for high-performance supercapacitor electrodes.NANOTECHNOLOGY,33(15),11.
MLA Zhao, Zongchen,et al."PPy coated nanoflower like CuCo2O4 based on in situ growth of nanoporous copper for high-performance supercapacitor electrodes".NANOTECHNOLOGY 33.15(2022):11.
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