Pd on Nanodiamond/Graphene in Hydrogenation of Propyne with Parahydrogen

doi:10.1021/acs.jpcc.1c08424

IMR OpenIR

	Pd on Nanodiamond/Graphene in Hydrogenation of Propyne with Parahydrogen
	Burueva, Dudari B.1,2; Sviyazov, Sergey, V 1,2; Huang, Fei 3; Prosvirin, Igor P.4; Bukhtiyarov, Andrey, V 4; Bukhtiyarov, Valerii, I 4; Liu, Hongyang 3; Koptyug, Igor, V 1
通讯作者	Burueva, Dudari B.(burueva@tomo.nsc.ru)
	2021-12-16
发表期刊	JOURNAL OF PHYSICAL CHEMISTRY C
ISSN	1932-7447
卷号	125 期号:49 页码:27221-27229
摘要	The catalytic behavior of Pd catalysts supported on a defective nanodiamond/graphene material (ND@G) was studied in propyne hydrogenation with parahydrogen, taking advantage of the possibility to control the character of metal distribution by changing metal loading. Two different catalysts were studied in this work: Pd-1/ND@G with a monoatomic Pd distribution (0.11 wt %) and Pd-n/ND@G comprising supported metal clusters (0.87 wt %). The monoatomic distribution of Pd in Pd-1/ND@G was confirmed by XPS and HAADF-STEM methods. This catalyst demonstrated an outstanding selectivity to propene (up to 100%) in propyne hydrogenation. The activity of the two Pd catalysts in pairwise H-2 addition to propyne was compared under the same experimental conditions by observing H-1 NMR signal enhancements provided by the parahydrogen-induced polarization (PHIP) effect. The enhancements produced by the Pd-1/ND@G catalyst were found to be ca. 6-fold larger than those observed with Pd-n/ND@G, indicating that the character of metal distribution has important consequences for the performance of a catalyst and its efficiency in terms of PHIP effects.
资助者	Russian Ministry of Science and Higher Education ; Ministry of Science and Higher Education of the Russian Federation
DOI	10.1021/acs.jpcc.1c08424
收录类别	SCI
语种	英语
资助项目	Russian Ministry of Science and Higher Education[075-152021-580] ; Ministry of Science and Higher Education of the Russian Federation[AAAA-A21121011390011-4]
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Materials Science
WOS类目	Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS记录号	WOS:000755081200018
出版者	AMER CHEMICAL SOC
引用统计	被引频次：5[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.imr.ac.cn/handle/321006/173484
专题	中国科学院金属研究所
通讯作者	Burueva, Dudari B.
作者单位	1.Int Tomog Ctr SB RAS, Lab Magnet Resonance Microimaging, Novosibirsk 630090, Russia 2.Novosibirsk State Univ, Novosibirsk 630090, Russia 3.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Peoples R China 4.Boreskov Inst Catalysis SB RAS, Novosibirsk 630090, Russia
推荐引用方式 GB/T 7714	Burueva, Dudari B.,Sviyazov, Sergey, V,Huang, Fei,et al. Pd on Nanodiamond/Graphene in Hydrogenation of Propyne with Parahydrogen[J]. JOURNAL OF PHYSICAL CHEMISTRY C,2021,125(49):27221-27229.
APA	Burueva, Dudari B..,Sviyazov, Sergey, V.,Huang, Fei.,Prosvirin, Igor P..,Bukhtiyarov, Andrey, V.,...&Koptyug, Igor, V.(2021).Pd on Nanodiamond/Graphene in Hydrogenation of Propyne with Parahydrogen.JOURNAL OF PHYSICAL CHEMISTRY C,125(49),27221-27229.
MLA	Burueva, Dudari B.,et al."Pd on Nanodiamond/Graphene in Hydrogenation of Propyne with Parahydrogen".JOURNAL OF PHYSICAL CHEMISTRY C 125.49(2021):27221-27229.