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Quadruple-action coatings provided by doping epoxy with inhibitor laden clay nanotubes functionalized with layer-by-layer of cross-bridged chitosan and anionic polyelectrolytes
Njoku, Demian, I1,5; Li, Bowen1; Khan, M. Saleem2,3; Chinonso, Uzoma Paul4; Njoku, Chigoziri N.1,5; Onyeachu, Ikenna B.5; Li, Ying1
通讯作者Li, Ying(liying@imr.ac.cn)
2021-08-01
发表期刊PROGRESS IN ORGANIC COATINGS
ISSN0300-9440
卷号157页码:20
摘要The present study divulges the quadruple-protective-action including combined enhanced barrier, active feedback protection, self-repairing and anti-fouling properties of epoxy composite coatings reinforced with benzotriazole-laden clay nanotubes capped with ferric ion and wrapped with layer-by-layer (LBL) assembly of chitosan/polyacrylic acid (CTS-PAA-CTS-PAA) and chitosan/polymethacrylic acid (CTS-PMMA-CTS-PMMA) polyelectrolytes cross-bridged with (+D)-epichlorohydrin. UV-vis spectrophotometric technique reveals the pHresponsive release of the loaded benzotriazole, while scanning vibrating electrode technique (SVET), electrochemical impedance spectroscopy (EIS) and optical techniques reveal the combined active feedback corrosion suppression and self-repairing of impressed defects. Additionally, confocal laser scanning microscopy (CLSM) and SEM techniques reveal the anti-bacterial properties. The experimental results confirmed that the new composite coatings exhibited unprecedented quadruple-action protection.
关键词Self-repairing Active feedback Impedance spectroscopy Hydrogel Composite coatings Antibacterial
资助者National Natural Science Fund of China ; World Bank Africa Centres of Excellence for Impact (ACE Impact) project
DOI10.1016/j.porgcoat.2021.106312
收录类别SCI
语种英语
资助项目National Natural Science Fund of China[51871227] ; National Natural Science Fund of China[51671198] ; World Bank Africa Centres of Excellence for Impact (ACE Impact) project[NUC/ES/507/1/304]
WOS研究方向Chemistry ; Materials Science
WOS类目Chemistry, Applied ; Materials Science, Coatings & Films
WOS记录号WOS:000670060200001
出版者ELSEVIER SCIENCE SA
引用统计
被引频次:13[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.imr.ac.cn/handle/321006/159958
专题中国科学院金属研究所
通讯作者Li, Ying
作者单位1.Chinese Acad Sci, Ctr Corros & Protect Mat, Inst Met Res, Wencui Rd 62, Shenyang 110016, Peoples R China
2.Chinese Acad Sci, Inst Met Res, Shenyang, Peoples R China
3.Chinese Acad Sci, Shenzhen Inst Adv Technol, Shenzhen 518000, Peoples R China
4.Chinese Acad Sci, Inst Met Res, Key Lab Nucl Mat & Safety Assessment, Shenyang 110016, Peoples R China
5.Fed Univ Technol Owerri, Africa Ctr Excellence Future Energies & Electroch, Owerri, Nigeria
推荐引用方式
GB/T 7714
Njoku, Demian, I,Li, Bowen,Khan, M. Saleem,et al. Quadruple-action coatings provided by doping epoxy with inhibitor laden clay nanotubes functionalized with layer-by-layer of cross-bridged chitosan and anionic polyelectrolytes[J]. PROGRESS IN ORGANIC COATINGS,2021,157:20.
APA Njoku, Demian, I.,Li, Bowen.,Khan, M. Saleem.,Chinonso, Uzoma Paul.,Njoku, Chigoziri N..,...&Li, Ying.(2021).Quadruple-action coatings provided by doping epoxy with inhibitor laden clay nanotubes functionalized with layer-by-layer of cross-bridged chitosan and anionic polyelectrolytes.PROGRESS IN ORGANIC COATINGS,157,20.
MLA Njoku, Demian, I,et al."Quadruple-action coatings provided by doping epoxy with inhibitor laden clay nanotubes functionalized with layer-by-layer of cross-bridged chitosan and anionic polyelectrolytes".PROGRESS IN ORGANIC COATINGS 157(2021):20.
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